I. PRODUCT AND COMPANY IDENTIFICATION

Product Name:

AMERIGUARD SM/GF-4 5W20 MOTOR OIL (PCMO)

Product Code:

AG-5W20-XX

 

 

Emergency Phone:

(800) 424-9300         (202) 483-7616         (CHEMTREC)

Poison Control Center:

(800) 222-1222

Company:

SBP, Inc.

9915 SO. 148 ST.

Omaha, Ne 68138

Information Phone:

(800) 233-4059          (402) 895-2202

Revision Number:

1

 

II. COMPOSITION/INFORMATION ON INGREDIENTS

 

Reportable Hazardous Substance(s) or Complex Substance(s) 

 Name

 CAS#

 Concentration*

 ZINC ALKYLDITHIOPHOSPHATE

 68649-42-3

 < 2.5%

   

* All concentrations are percent by weight unless material is a gas.  Gas concentrations are in percent by volume.

 

SECTION 3

 HAZARDS IDENTIFICATION

 

This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).

 

 

 

POTENTIAL HEALTH EFFECTS

 Low order of toxicity.  Excessive exposure may result in eye, skin, or respiratory irritation.  High-pressure injection under skin may cause serious damage.

 

 

 NFPA Hazard ID:

Health:    0

Flammability:   1

Reactivity:   0

 HMIS Hazard ID:

Health:    0

Flammability:   1

Reactivity:   0

 

 

NOTE:   This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. 

 

IV. FIRST-AID MEASURES

Inhalation:

If overcome by vapor from hot product, immediately remove victim to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately.  If overexposed to oil mist, remove from further exposure. 

Eyes:

Use eye wash to remove a chemical from the eye. Flush the affected eye for at least fifteen minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention if irritation persists.

Skin Contact:

Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists.

Ingestion:

Do not induce vomiting and seek medical attention immediately.  Provide medical care provider with this MSDS. 

Notes to Doctor:

Aspiration during swallowing or vomiting may severely damage the lungs.

 

V. FIRE FIGHTING MEASURES

Flammability Summary:

Not combustible/ not flammable.

Extinguishing Media:

Use water spray, foam, carbon dioxide, or dry chemical extinguishing agents. Water spray or fog may also be effective for extinguishing if swept across the base of the fire. Water can also be used to absorb heat and keep exposed material from being damaged by fire. 

Fire and/or Explosion Hazards:

Material may be ignited only if preheated to temperatures above the high flash point, for example in a fire.  

Fire Fighting Methods and Protection:

Do not enter fire area without proper protection including self- contained breathing apparatus and full protective equipment.  Use methods for the surrounding fire.

Hazardous Combustion Products:

Carbon dioxide, Carbon monoxide,

 

 

VI. ACCIDENTAL RELEASE MEASURES

Personal Precautions and Equipment:

No adverse health affects expected from the clean-up of  spilled material. Follow personal protective equipment recommendations found in Section VIII of this MSDS. 

Methods for Clean-up:

Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section VIII at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. 

 

VII. HANDLING AND STORAGE

Handling Technical Measures and Precautions:

No special handling instructions due to toxicity.  

Storage Technical Measures and Conditions:

Store in a cool dry ventilated location. Isolate from incompatible materials and conditions. Keep container(s) closed.  Do not expose to extreme temperatures or flames. 

 

VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION

EXPOSURE LIMIT VALUES

 

 

 

Exposure limits/standards for materials that can be formed when handling this product:   When mists / aerosols can occur, the following are recommended:  5 mg/m³ - ACGIH TLV,  10 mg/m³ - ACGIH STEL, 5 mg/m³ - OSHA PEL. 

 

 

NOTE: Limits/standards shown for guidance only.  Follow applicable regulations.

 

ENGINEERING CONTROLS

 

The level of protection and types of controls necessary will vary depending upon potential exposure conditions.  Control measures to consider:

 No special requirements under ordinary conditions of use and with adequate ventilation.

 

PERSONAL PROTECTION

 

Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation.  Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. 

 

Respiratory Protection:   If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate.  Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable.  Types of respirators to be considered for this material include:

 No special requirements under ordinary conditions of use and with adequate ventilation.

 

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.  Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.

 

Hand Protection:   Any specific glove information provided is based on published literature and glove manufacturer data.  Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:

 No protection is ordinarily required under normal conditions of use.

 

Eye Protection:   If contact is likely, safety glasses with side shields are recommended.

 

Skin and Body Protection:    Any specific clothing information provided is based on published literature or manufacturer data.  The types of clothing to be considered for this material include:

 No skin protection is ordinarily required under normal conditions of use.  In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact.

 

Specific Hygiene Measures:   Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking.  Routinely wash work clothing and protective equipment to remove contaminants.  Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping.

 

 

ENVIRONMENTAL CONTROLS

 See Sections  6,  7, 12, 13.

 

 

IX. PHYSICAL AND CHEMICAL PROPERTIES

Typical physical and chemical properties are given below.   Consult the Supplier in Section 1 for additional data.

 

GENERAL INFORMATION

Physical State:    Liquid

Color:   Amber

Odor:   Characteristic

Odor Threshold:   N/D

 

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION

Relative Density (at 15 C ):    0.86  

Flash Point [Method]:     >200C  (392F) [ ASTM D-92]

Flammable Limits (Approximate volume % in air):   LEL:  0.9     UEL: 7.0 

Autoignition Temperature:  N/D

Boiling Point / Range:   N/D

Vapor Density (Air = 1):   N/D

Vapor Pressure:   < 0.013 kPa (0.1 mm Hg) at 20 C

Evaporation Rate (n-butyl acetate = 1):   N/D

pH:   N/A

Log Pow (n-Octanol/Water Partition Coefficient):   > 3.5

Solubility in Water:   Negligible

Viscosity:   48 cSt  (48 mm2/sec ) at 40 C  |  8.5 cSt  (8.5 mm2/sec) at 100C

Oxidizing Properties:  See Sections 3, 15, 16.

 

OTHER INFORMATION

Freezing Point:   N/D

Melting Point:   N/A

Pour Point:      -24°C  (-11°F)  

DMSO Extract (mineral oil only), IP-346:    < 3 %wt

 

 

X. STABILITY AND REACTIVITY

 

STABILITY:  Material is stable under normal conditions.

 

CONDITIONS TO AVOID:  Excessive heat. High energy sources of ignition.

 

MATERIALS TO AVOID:   Strong oxidizers

 

HAZARDOUS DECOMPOSITION PRODUCTS:  Material does not decompose at ambient temperatures.

 

HAZARDOUS POLYMERIZATION:  Will not occur.

 

 

XI. TOXICOLOGICAL INFORMATION

 

ACUTE TOXICITY

 Route of Exposure

 Conclusion / Remarks

Inhalation

 

Toxicity (Rat): LC50 > 5000 mg/m3

Minimally Toxic. Based on test data for structurally similar materials.

Irritation: No end point data.

Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.

 

 

Ingestion

 

Toxicity (Rat): LD50 > 5000 mg/kg

Minimally Toxic. Based on test data for structurally similar materials.

 

 

Skin

 

Toxicity (Rabbit): LD50 > 5000 mg/kg

Minimally Toxic. Based on test data for structurally similar materials.

Irritation (Rabbit): Data available.

Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.

 

 

Eye

 

Irritation (Rabbit): Data available.

May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.

 

CHRONIC/OTHER EFFECTS

             For the product itself:

 Diesel engine oils:  Not carcinogenic in animals tests.  Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies.

Oils that are used in gasoline engines may become hazardous and display the following properties:  Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains polycyclic aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products.

 

Contains:

Base oil severely refined:  Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals.

 

 

Additional information is available by request.

 

The following ingredients are cited on the lists below:  None.

 

 

--REGULATORY LISTS SEARCHED--

 1 = NTP CARC

 3 = IARC 1

 5 = IARC 2B

 2 = NTP SUS

 4 = IARC 2A

 6 = OSHA CARC

 

 

XII. ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials.

 

ECOTOXICITY   

             Material -- Not expected to be harmful to aquatic organisms.

 

MOBILITY

             Base oil component -- Low solubility and floats and is expected to migrate from water to the land.  Expected to partition to sediment and wastewater solids.

 

PERSISTENCE AND DEGRADABILITY

Biodegradation:

             Base oil component --  Expected to be inherently biodegradable  

 

BIOACCUMULATION POTENTIAL

             Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.

 

 

   

XIII. DISPOSAL CONSIDERATIONS

Disposal of Packaging:

Recycle containers whenever possible.

Disposal Methods:

Dispose of according to Federal, State, Local, or Provincial regulations.  Recycle used oil.

 

XIV. TRANSPORTATION INFORMATION

 

 

 

DOT & IMDG:  NOT RESTRICTED

 

XV. REGULATORY INFORMATION

OSHA HAZARD COMMUNICATION STANDARD:   When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200.

 

NATIONAL CHEMICAL INVENTORY LISTING:   DSL, KECI, TSCA

               Special Cases:

 

 Inventory

 Status

 AICS

 Restrictions Apply

 ELINCS

 Restrictions Apply

 

 

EPCRA:  This material contains no extremely hazardous substances.

  

     

 

SARA (311/312) REPORTABLE HAZARD CATEGORIES:   None.

 

SARA (313) TOXIC RELEASE INVENTORY:

Chemical Name

CAS Number

Typical Value

ZINC ALKYLDITHIOPHOSPHATE

68649-42-3

< 2.5%

 

 

The Following Ingredients are Cited on the Lists Below: 

Chemical Name

CAS Number

List Citations

DIPHENYLAMINE

122-39-4

5, 18

ZINC ALKYLDITHIOPHOSPHATE

68649-42-3

13, 15, 17

ZINC DITHIOPHOSPHATE

68649-42-3

15

 

--REGULATORY LISTS SEARCHED--

1 = ACGIH ALL

6 = TSCA 5a2

11 = CA P65 REPRO

16 = MN RTK

 2 = ACGIH A1

7 = TSCA 5e

12 = CA RTK

17 = NJ RTK

3 = ACGIH A2

8 = TSCA 6

13 = IL RTK

18 = PA RTK

4 = OSHA Z

9 = TSCA 12b

14 = LA RTK

19 = RI RTK

5 = TSCA 4

10 = CA P65 CARC

15 = MI 293

 

 

Code key: CARC=Carcinogen; REPRO=Reproductive

 

 

XVI. ADDITIONAL INFORMATION

Disclaimer:

This material safety data sheet and the information it contains is offered to you in good faith as accurate.  We have reviewed any information contained in the data sheet which we have received from outside sources and we believe the information to be correct, but cannot guarantee its accuracy or completeness.  Health and safety precautions in this data sheet may not be adequate for all individuals and/or situations.  It is the user's obligation to evaluate and use this product in a safe manner and to comply with all applicable laws and regulations.  No statement made in this data sheet shall be construed as permission or recommendation for the use of any product in a manner that might infringe existing patents.  No warranty is made, either expressed or implied.