I. PRODUCT AND COMPANY IDENTIFICATION

Product Name:

AMERIGUARD CJ-4/CI-4 PLUS/CI-4/CH-4/SM

Product Code:

AG-1540-XX

 

 

Emergency Phone:

(800) 424-9300         (202) 483-7616         (CHEMTREC)

Poison Control Center:

(800) 222-1222

Company:

SBP

9915 SO. 148 ST

Omaha, Ne 68138

Information Phone:

(800) 233-4059          (402) 895-2202

Revision Number:

1

 

II. COMPOSITION/INFORMATION ON INGREDIENTS

Reportable Hazardous Substance(s) or Complex Substance(s) 

 Name

 CAS#

 Concentration*

 ZINC DITHIOPHOSPHATE

 68649-42-3

 < 2.5%

   

* All concentrations are percent by weight unless material is a gas.  Gas concentrations are in percent by volume

 

III. HAZARDS IDENTIFICATION

Target Organs Potentially Affected by Exposure:

None known,

Chemical Interactions That Change Toxicity:

No chemical interaction known to affect toxicity.,

 

Immediate (Acute) Health Effects by Route of Exposure:

Inhalation Irritation:

Breathing oil mist in concentrations that exceed the TLV and PEL may result in respiratory discomfort and irritation. 

Skin Contact:

Can cause minor skin irritation, defatting, and dermatitis. 

Eye Contact:

Can cause minor irritation. 

Ingestion Irritation:

Although this product has a low order of acute oral toxicity, aspiration of minute amounts into the lungs during ingestion or vomiting may cause mild to severe pulmonary injury and possibly death. 

 

Long-Term (Chronic) Health Effects:

Carcinogenicity:

Not a carcinogen according to NTP, IARC, or OSHA. 

Reproductive and Developmental Toxicity:

No data available to indicate product or any components present at greater than 0.1% may cause birth defects. 

Mutagenicity:

No data available.

Inhalation:

Breathing oil mist in concentrations that exceed the TLV and PEL may result in respiratory discomfort and irritation.

Skin Contact:

Upon prolonged or repeated contact, can cause minor skin irritation, defatting, and dermatitis.

 

HMIS Ratings:

Health:

0

Flammability:

1

Reactivity:

0

PPE:

B

0 - Least               1 - Slight               2 - Moderate               3 - High               4 - Extreme

 

IV. FIRST-AID MEASURES

Inhalation:

If overcome by vapor from hot product, immediately remove victim to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately.  If overexposed to oil mist, remove from further exposure. 

Eyes:

Use eye wash to remove a chemical from the eye. Flush the affected eye for at least fifteen minutes. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Seek medical attention if irritation persists.

Skin Contact:

Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists.

Ingestion:

Do not induce vomiting and seek medical attention immediately.  Provide medical care provider with this MSDS. 

Notes to Doctor:

Aspiration during swallowing or vomiting may severely damage the lungs.

 

V. FIRE FIGHTING MEASURES

Flammability Summary:

Not combustible/ not flammable.

Extinguishing Media:

Use water spray, foam, carbon dioxide, or dry chemical extinguishing agents. Water spray or fog may also be effective for extinguishing if swept across the base of the fire. Water can also be used to absorb heat and keep exposed material from being damaged by fire. 

Fire and/or Explosion Hazards:

Material may be ignited only if preheated to temperatures above the high flash point, for example in a fire.  

Fire Fighting Methods and Protection:

Do not enter fire area without proper protection including self- contained breathing apparatus and full protective equipment.  Use methods for the surrounding fire.

Hazardous Combustion Products:

Carbon dioxide, Carbon monoxide,

 

 

VI. ACCIDENTAL RELEASE MEASURES

Personal Precautions and Equipment:

No adverse health affects expected from the clean-up of  spilled material. Follow personal protective equipment recommendations found in Section VIII of this MSDS. 

Methods for Clean-up:

Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section VIII at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. 

 

VII. HANDLING AND STORAGE

Handling Technical Measures and Precautions:

No special handling instructions due to toxicity.  

Storage Technical Measures and Conditions:

Store in a cool dry ventilated location. Isolate from incompatible materials and conditions. Keep container(s) closed.  Do not expose to extreme temperatures or flames. 

 

VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Measures:

Local exhaust ventilation or other engineering controls may be required when handling or using this product to avoid overexposure.  

 

Respiratory Protection:

Respiratory protection may be required to avoid overexposure when handling this product. General or local exhaust ventilation is the preferred means of protection. Use a respirator if general room ventilation is not available or sufficient to eliminate symptoms. 

Respirator Type(s):

None required where adequate ventilation is provided. If airborne concentrations are above the applicable exposure limits, use NIOSH/MSHA approved respiratory protection.

Eye Protection:

Wear safety glasses when handling this product if there is a likelihood of contact with eyes. 

Skin Protection:

Where use can result in skin contact, practice good personal hygiene and wear impervious gloves. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work. 

Gloves:

Neoprene

 

 

IX. PHYSICAL AND CHEMICAL PROPERTIES

Typical physical and chemical properties are given below.   Consult the Supplier in Section 1 for additional data.

 

GENERAL INFORMATION

Physical State:    Liquid

Color:   Amber

Odor:   Characteristic

Odor Threshold:   N/D

 

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION

Relative Density (at 15 C ):    0.88  

Flash Point [Method]:     228C  (442F) [ ASTM D-92]

Flammable Limits (Approximate volume % in air):   LEL:  0.9     UEL: 7.0 

Autoignition Temperature:  N/D

Boiling Point / Range:    > 316C  (600F)

Vapor Density (Air = 1):   > 2 at 101 kPa

Vapor Pressure:   < 0.013 kPa (0.1 mm Hg) at 20 C

Evaporation Rate (n-butyl acetate = 1):   N/D

pH:   N/A

Log Pow (n-Octanol/Water Partition Coefficient):   > 3.5

Solubility in Water:   Negligible

Viscosity:   109 cSt  (109 mm2/sec ) at 40 C  |  14.5 cSt  (14.5 mm2/sec) at 100C

Oxidizing Properties:  See Sections 3, 15, 16.

 

OTHER INFORMATION

Freezing Point:   N/D

Melting Point:   N/A

Pour Point:      -30°C  (-22°F)  

DMSO Extract (mineral oil only), IP-346:    < 3 %wt

 

X. STABILITY AND REACTIVITY

Stability:

Stable under normal conditions. 

Conditions to Avoid:

Temperatures above the high flash point of this combustible material in combination with sparks, open flames, or other sources of ignition. 

Materials to Avoid/Chemical Incompatibility:

Strong oxidizing agents

Hazardous Decomposition Products:

Carbon monoxide, sulfur oxides, aldehydes, and other petroleum decomposition products in the case of incomplete combustion.  Oxides of nitrogen, phosphorus, calcium, copper, magnesium, sodium, and hydrogen sulfide may also be present.

 

XI. TOXICOLOGICAL INFORMATION

ACUTE TOXICITY

 Route of Exposure

 Conclusion / Remarks

Inhalation

 

Toxicity (Rat): LC50 > 5000 mg/m3

Minimally Toxic. Based on test data for structurally similar materials.

Irritation: No end point data.

Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.

 

 

Ingestion

 

Toxicity (Rat): LD50 > 2000 mg/kg

Minimally Toxic. Based on test data for structurally similar materials.

 

 

Skin

 

Toxicity (Rabbit): LD50 > 2000 mg/kg

Minimally Toxic. Based on test data for structurally similar materials.

Irritation (Rabbit): Data available.

Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.

 

 

Eye

 

Irritation (Rabbit): Data available.

May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.

 

CHRONIC/OTHER EFFECTS

             For the product itself:

 Diesel engine oils:  Not carcinogenic in animals tests.  Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies.

Oils that are used in gasoline engines may become hazardous and display the following properties:  Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains polycyclic aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products.

 

Contains:

Base oil severely refined:  Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals.

 

 

Additional information is available by request.

 

The following ingredients are cited on the lists below:  None.

 

 

--REGULATORY LISTS SEARCHED--

 1 = NTP CARC

 3 = IARC 1

 5 = IARC 2B

 2 = NTP SUS

 4 = IARC 2A

 6 = OSHA CARC

 

 

 

 

XII. ECOLOGICAL INFORMATION

Overview:

Moderate ecological hazard. This product may be dangerous to plants and/or wildlife.

Mobility:

No data

Persistence:

No data

Bioaccumulation:

No data

Degradability:

No data

Ecological Toxicity Data:

                       0

 

XIII. DISPOSAL CONSIDERATIONS

Disposal of Packaging:

Recycle containers whenever possible.

Disposal Methods:

Dispose of according to Federal, State, Local, or Provincial regulations.  Recycle used oil.

 

XIV. TRANSPORTATION INFORMATION

 

 

 

DOT & IMDG:  NOT RESTRICTED

 

XV. REGULATORY INFORMATION

OSHA HAZARD COMMUNICATION STANDARD:   When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200.

 

NATIONAL CHEMICAL INVENTORY LISTING:   TSCA, DSL, KECI

               Special Cases:

 

 Inventory

 Status

 AICS

 Restrictions Apply

 ELINCS

 Restrictions Apply

 IECSC

 Restrictions Apply

  EPCRA:  This material contains no extremely hazardous substances.

  

     

 

SARA (311/312) REPORTABLE HAZARD CATEGORIES:   None.

 

SARA (313) TOXIC RELEASE INVENTORY:

Chemical Name

CAS Number

Typical Value

ZINC DITHIOPHOSPHATE

68649-42-3

< 2.5%

 

 

The Following Ingredients are Cited on the Lists Below: 

Chemical Name

CAS Number

List Citations

DIPHENYLAMINE

122-39-4

5, 18

ZINC DITHIOPHOSPHATE

68649-42-3

13, 15, 17

 

--REGULATORY LISTS SEARCHED--

1 = ACGIH ALL

6 = TSCA 5a2

11 = CA P65 REPRO

16 = MN RTK

 2 = ACGIH A1

7 = TSCA 5e

12 = CA RTK

17 = NJ RTK

3 = ACGIH A2

8 = TSCA 6

13 = IL RTK

18 = PA RTK

4 = OSHA Z

9 = TSCA 12b

14 = LA RTK

19 = RI RTK

5 = TSCA 4

10 = CA P65 CARC

15 = MI 293

 

 

Code key: CARC=Carcinogen; REPRO=Reproductive

 

 

XVI. ADDITIONAL INFORMATION

Disclaimer:

This material safety data sheet and the information it contains is offered to you in good faith as accurate.  We have reviewed any information contained in the data sheet which we have received from outside sources and we believe the information to be correct, but cannot guarantee its accuracy or completeness.  Health and safety precautions in this data sheet may not be adequate for all individuals and/or situations.  It is the user's obligation to evaluate and use this product in a safe manner and to comply with all applicable laws and regulations.  No statement made in this data sheet shall be construed as permission or recommendation for the use of any product in a manner that might infringe existing patents.  No warranty is made, either expressed or implied.